E-numbers / E303 Antioxidant

Potassium ascorbate

also: Potassium salt of ascorbic acid · Vitamin C (potassium form)
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The short version

The potassium salt of vitamin C, used as an antioxidant to stop food browning and going rancid. Not permitted as a food additive in the UK or EU.

Why it's worth knowing

E303 is not authorised in UK or EU food. If you see it listed on a product, that product may not comply with UK food additive law. Related permitted antioxidants to recognise are E300 (ascorbic acid), E301 (sodium ascorbate) and E302 (calcium ascorbate).

What is it?

Potassium ascorbate is the potassium salt of ascorbic acid (vitamin C). It is a white crystalline powder that dissolves readily in water. Like other ascorbate salts, it delivers the same antioxidant function as vitamin C but with a small amount of potassium rather than sodium or calcium as the accompanying cation.

What does it do?

As an antioxidant, potassium ascorbate donates electrons to free radicals and to oxygen, interrupting the oxidation chain reactions that cause food to brown, go rancid, or lose colour. It also acts as a reducing agent in food systems, regenerating other antioxidants such as tocopherols (vitamin E). In meat products it can accelerate colour development by reducing metmyoglobin back to the red oxymyoglobin form.

Where you will see it

In countries where it is permitted (such as Australia and New Zealand), potassium ascorbate is used in beverages, processed meats, fruit products, and packaged fresh produce to preserve colour and extend shelf life. It is not authorised for use in UK or EU food products. It would appear on a label as 'potassium ascorbate' or 'antioxidant (potassium ascorbate)', but E303 is not a valid E number for use on UK labels because the substance is not approved.

What the science says

Regulatory non-approval in the UK and EU

E303 does not appear in Annex II of assimilated EU Regulation 1333/2008 on food additives, which is the authorised list carried forward into UK law after Brexit. The UK FSA approved-additives list confirms the gap: E300, E301, E302, and E304 are all listed as permitted antioxidants from the ascorbate family, but E303 is absent. A food product sold in the UK containing E303 as a declared additive would not comply with current UK food additive regulations.

E303 potassium ascorbate is not included in the UK FSA list of approved food additives or in the assimilated EU Regulation 1333/2008 Annex II list of permitted food additives.

UK Food Standards Agency, Approved Additives and E Numbers (food.gov.uk)regulatory

Ascorbate antioxidants: shared chemistry, different regulatory fates

Potassium ascorbate shares the same core antioxidant mechanism as its approved relatives, ascorbic acid (E300) and sodium ascorbate (E301). Scientific literature on the safety of ascorbate salts generally treats them together, since the active moiety, the ascorbate anion, is identical regardless of the cation. EFSA and its predecessor the EU Scientific Committee on Food evaluated the ascorbates as a class, and ascorbic acid and its sodium, calcium, and ester forms were all authorised. Potassium ascorbate was not included in that authorisation.

Ascorbic acid and its salts share the same mechanism of action and the ascorbate anion is the active antioxidant species in all cases; the cation (sodium, calcium, potassium) does not alter antioxidant function.

PMC5076701 - The Use of Ascorbic Acid as a Food Additive: Technical-Legal Issues, Nutrients2016regulatory review

Permitted status in other jurisdictions

Potassium ascorbate is authorised as a food antioxidant in Australia and New Zealand under their respective food standards codes. This divergence from UK and EU rules means that products imported from those countries may lawfully contain it under their domestic rules, but the same product sold in the UK would need reformulation or an exemption. The substance is not on the US FDA's generally recognised as safe (GRAS) list as a food additive either, though ascorbic acid and sodium ascorbate hold GRAS status.

Potassium ascorbate is permitted as a food antioxidant under Food Standards Australia New Zealand (FSANZ) food standards.

Food Standards Australia New Zealand (FSANZ), Food Additives Permittedregulatory

Where it stands with the regulators

Status
Not a permitted food additive in the UK or EU
Legal basis
UK FSA approved-additives list and assimilated EU Regulation 1333/2008 Annex II. E303 does not appear in either list. Permitted ascorbate antioxidants in UK/EU are E300 (ascorbic acid), E301 (sodium ascorbate), E302 (calcium ascorbate), and E304 (fatty acid esters of ascorbic acid).
History
Potassium ascorbate was not included when the EU evaluated and authorised the ascorbate family of antioxidants under Regulation 1333/2008. The omission appears to reflect a lack of formal application or data submission for this specific salt rather than a specific safety finding against it. The substance remains unapproved in the UK following the assimilation of EU food additive law post-Brexit. It is approved in Australia and New Zealand.

Who should be careful

Anyone buying food in the UK should not ordinarily encounter E303, as it is not a permitted additive here. If a UK-sold product does list potassium ascorbate or E303, that may indicate a mislabelled import. People on potassium-restricted diets (for example, those with kidney disease) should note that all potassium-containing food additives add to total dietary potassium intake, though the amounts from additives are generally small relative to potassium from food itself.

The honest read

Cutting through the noise

The absence of E303 from UK and EU approved lists does not mean the substance is harmful. Its close relatives, including the widely used E300 (ascorbic acid, plain vitamin C) and E301 (sodium ascorbate), are authorised and extensively reviewed. The potassium salt simply was never the subject of a formal EFSA or UK approval application in the food additive context. The practical consequence for UK shoppers is that it should not be present in UK food; if it is, that is a compliance question, not a toxicological one. The science on ascorbates as a class is long-standing and well-characterised.

Related additives

Common questions

Is E303 banned in the UK?

E303 is not authorised in the UK, meaning it is not on the approved list of food additives permitted for use in UK food products. It was also not authorised under EU Regulation 1333/2008, which UK law carried forward after Brexit. 'Not permitted' and 'banned' have the same practical effect for food manufacturers: it cannot lawfully be used as a food additive in UK or EU products.

Why is E303 not approved when E300 and E301 (both vitamin C derivatives) are?

The EU and UK approve additives individually following a formal application and safety evaluation. E300 (ascorbic acid), E301 (sodium ascorbate), and E302 (calcium ascorbate) each went through that process and received authorisation. Potassium ascorbate appears never to have been the subject of a formal approval application to EFSA or the earlier EU scientific committees in the food additive context, so it was simply not included on the list. The absence reflects administrative process rather than a specific safety finding.

What foods contain E303?

No UK or EU food products should legally contain E303 as a declared food additive. In countries where it is permitted, such as Australia and New Zealand, it can appear in beverages, processed meats, fruit products, and packaged produce. If you see it on a UK product label, that product may not meet UK food additive requirements.

Is E303 vegan?

Yes. Potassium ascorbate is produced synthetically from ascorbic acid and potassium compounds. It contains no animal-derived ingredients and is suitable for vegans and vegetarians.

Sources

Last reviewed: 20 June 2026

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